杜浩 研究员
学历/学位：研究生/博士
研究方向：两性金属矿物高效清洁利用的应用基础研究与新技术研发
邮箱：hdu@ipe.ac.cn
地址：北京市海淀区中关村北二街1号
邮编：100190
简历介绍
杜浩，中国科学院过程工程研究所研究员、博士生导师，研究部副主任，中国科学院大学岗位教授。1997年在北京科技大学获冶金材料学学士学位；2002年在美国南达科他矿业科技大学获冶金材料硕士学位，研究方向为高分子复合材料；2007年在美国犹他大学获冶金工程博士学位，主要研究方向为浮选化学以及矿物资源的综合利用。2007年12月至2009年6月，在犹他大学从事博士后研究工作，科研方向为矿物分离加工与综合利用及催化合成高能燃料。他从事的高级仪器分析与计算机模拟研究表面化学开拓了浮选化学研究的新领域。2009年8月以“引进杰出技术人才”称号被引进到中国科学院过程工程研究所工作至今。针对我国重大战略金属矿产资源利用率低、环境污染严重等难题，牵头构建了以高级氧化技术为核心的湿法冶金新理论，开发了微气泡、电场强化等多种以活性氧量化调控为核心的外场强化新方法，极大地推动了两性金属矿物清洁利用的工艺创新与产业化推广；与河钢承钢合作建成了国际首套具有全部自主知识产权的“万吨级钒渣钒铬共提示范工程”、“千吨级高纯钒短流程清洁制备示范工程”等并实现稳定运行，新工艺环境、经济效益显著，在行业内产生重要影响。近年来主持国家部委、中科院、企业委托等项目20余项，撰写英文专著（章节）1部、中文专著1部，发表学术论文150余篇，其中SCI论文90篇，申请专利110余项，其中已授权75项，获省部级科技进步奖7项。
代表论著
一、专著
1. Hao Du, Xihui Yin, Orhan Ozdemir, Jin Liu, Xuming Wang, Shili Zheng, and Jan D. Miller, Chapter 4 Molecular Dynamics Simulation Analysis of Solutions and Surfaces in Nonsulfide Flotation Systems, Molecular Modeling for the Design of Novel Performance Chemicals and Materials, Beena Rai, CRC Press, Taylor & Francis Group, 2012, P108-151, United States
2. 张懿，曹绍涛，杜浩，李会泉，马淑花，齐涛，王少娜，王晓辉，徐红彬，薛天艳，阎文艺，张亦飞，郑诗礼. 亚熔盐清洁生产技术与资源高效利用，北京：化学工业出版社，2016年8月，795千字，ISBN：9787122259400
二、代表性文章
1. Chenjie Han, Yeqing Lyu, Shaona Wang, Biao Liu, Yi Zhang, Hao Du*. Role of Noncovalent Interactions on the Electrocatalytic Oxidation of Ethanol in Alkali Metal Hydroxide Solutions[J]. ACS Applied Materials & Interfaces, 2022, 14(4): 5318-5327.
2. Jianzhang Wang, Shaona Wang, Afolabi Olayiwola, Na Yang, Biao Liu, Jan J.Weigand, Marco Wenzael, Hao Du*. Recovering valuable metals from spent hydrodesulfurization catalyst via blank roasting and alkaline leaching[J]. Journal of Hazardous Materials, 2021, 416: 125849
3. Yaru Wang, Yeqing Lyu, Shaona Wang, Hao Du*. Generation of reactive oxygen species from oxygen microbubbles in phosphoric acid solution and its application of ferrous iron oxidation[J]. Journal of the Taiwan Institute of Chemical Engineers, 2021:1-9
4. Shaona Wang, Jianzhang Wang, Biao Liu, Yeqing Lv, Yi Zhang, and Hao Du*. Experimental Determination of Phase Equilibria in the Quaternary NaOH-Na3VO4-Na2MoO4-H2O System at 298.15–353.15 K[J]. Journal of Chemical & Engineering Data, 2021, 66: 85-93
5. Feng Gao, Afolabi Uthmon Olayiwola, Biao Liu, Shaona Wang, Hao Du*, Jianzhong Li, Xindong Wang, Donghui Chen, Yi Zhang. Review of vanadium production part I primary resources [J]. Mineral Processing and Extractive Metallurgy Review, 2021:1-23
6. 王少娜，吕页清，刘彪，杜浩*，白丽，王海旭，王新东，李兰杰，张懿. 钒渣亚熔盐法钒铬共提工艺清洁生产评价. 中国有色金属学报，2021,31（3）:736-747
7. 王少娜，杜浩*，贾美丽，祁健，陈树军，李兰杰，王宝华. 高纯V2O5制备工艺研究. 河北冶金，2021，8：9-15
8. 王亚茹，吕页清，王少娜，杜浩*. 微气泡强化磷酸介质中Fe2+高效氧化研究[J]. 过程工程学报，2020:1-9
9. 王少娜，白丽，王新东，吕页清，刘彪，杜浩*，王海旭，李兰杰，张懿. 钒渣提钒行业清洁生产评价指标体系的建立[J]. 环境生态学, 2020,2(10):43-49
10 .Bo Pan, Biao Liu, Shaona Wang, Marco Wenzel, Jan J.Weigand, Man Feng, Hao Du*, Yi Zhang. Ammonium vanadate/ammonia precipitation for vanadium production from a high vanadate to sodium ratio solution obtained via membrane electrolysis method. Journal of Cleaner Production, 2020, 263(121357):1-9
11. Shaona Wang, Man Feng, Hao Du*, Jan J.Weigand, Yi Zhang, Xindong Wang. Determination of metastable zone width, induction time and primary nucleation kinetics for cooling crystallization of sodium orthovanadate from NaOH solution. Journal of Grystal Growth, 2020, 545 (125721):1-8
12. Man Feng, Marco Wenzel, Shaona Wang, Hao Du*, Yi Zhang, Jan J.Weigand. Separation of Na3VO4 and Na2CrO4 from high alkalinity solutions by solvent extracton. Separation and Purification Technology, 2020, 117282: 1-8
13. 王少娜，靳星，刘彪，赵备备，李兰杰，李明，杜浩*，张懿. ICP-OES法测定钒的光谱干扰研究.光谱学与光谱分析，2020,40:2283-2288
14. Yeqing Lyu, Yaru Wang, Shaona Wang, Biao Liu, Hao Du*. Potassium Hydroxide Concentration-Dependent Water Structure on the Quartz Surface Studied by Combining Sum-Frequency Generation (SFG) Spectroscopy and Molecular Simulations. Langmuir. 2019, 35:11651-11661
15. Xinran Wang, Xuanxuan Bi, Shili Zheng, Shaona Wang, Yi Zhang, Hao Du*, Jun Lu. High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic–Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries. Advanced Energy Materials, 2018, 8, 1801978
16. Xinran Wang, Shaona Wang, Yi Zhang, Hao Du*. Organic vanadium oxy-acetylacetonate as electro-active anode material with high capacity and rate performance for lithium-ion batteries. Journal of Materials Science. 2018, 53(13): 9701-9709
17. Meng Li, Biao Liu, Xinran Wang, Xiaobin Yu, Shili Zheng, Hao Du*, David Dreisinger, Yi Zhang. A promising approach to recover a spent SCR catalyst: Deactivation by arsenic and alkaline metals and catalyst regeneration. Chemical Engineering Journal. 2018, 342: 1-8
18. Kanghua Wu, Yaru Wang, Xinran Wang, Shaona Wang, Biao Liu, Zhang, Hao Du*. Co-extraction of vanadium and chromium from high Yi chromium containing vanadium slag by low-pressure liquid phase oxidation method. Journal of Cleaner Production. 2018, 203: 873-884
19. Xinran Wang, Xuanxuan Bi, Shaona Wang, Yi Zhang, Hao Du*, Jun Lu. High-Rate and Long-Term Cycle Stability of Li-S Batteries Enabled by Li2S/TiO2-Impregnated Hollow Carbon Nanofiber Cathodes. ACS Applied Materials & Interfaces. 2018, 10(19): 16552-16560
20. Xiaobin Yu, ZhonghangWang, Yeqing Lv, ShaonaWang, Shili Zheng, Hao Du,* and Yi Zhang. Effect of microbubble diameter, alkaline concentration and temperature on reactive oxygen species concentration. Journal of Chemical Technology & Biotechnology, 2017, 92: 1738-1745
21. Yeqing Lv，Xinran Wang, Xiaobin Yu, Shili Zheng，Shaona Wang，Yi Zhang，Hao Du*. Adsorption behaviors and vibrational spectra of hydrogen peroxide molecules at quartz/water interfaces. Physical Chemistry Chemical Physics, 2017, 19(10): 7054-7061
22. Meng Li, Biao Liu, Shili Zheng, Shaona Wang, Hao Du*, D.B.Dreisinger**, Yi Zhang. A cleaner vanadium extraction method featuring non-salt roasting and ammonium bicarbonate leaching. Journal of Cleaner Production, 2017, 149: 206-217
23. Meng Li, Hao Du*, Shili Zheng, Shaona Wang, Yang Zhang, Biao Liu, D.B.Dreisinger, Yi Zhang. Extraction of vanadium from vanadium slag via non-salt roasting and ammonium oxalate leaching. JOM, 2017, 69: 1970-1975
24. Meng Li, Shili Zheng, Biao Liu, Hao Du*, D.B.Dreisinger, Leili Tafaghodi, Yi Zhang. The leaching kinetics of cadmium from hazardous Cu-Cd zinc plant residues. Waste Management, 2017, 65: 128-138
25. Bo Pan, Wei Jin, Biao Liu, Shili Zheng, Shaona Wang, Hao Du*, Yi Zhang. Cleaner Production of Vanadium Oxides by Cation-Exchange Membrane Assisted Electrolysis of Sodium Vanadate Solution. Hydrometallurgy, 2017,169: 440-446
26. Longjie Liu, Hao Du*, Yang Zhang, Shili Zheng, Yi Zhang. Leaching of chromite ore in concentrated KOH by catalytic oxidation using CuO as catalyst. Trans. Nonferrous Met. Soc. China, 2017, 27: 891−900
27. Meng Li, Shili Zheng, Biao Liu, Shaona Wang, D.B. Dreisinger, Yang Zhang, Hao Du*, Yi Zhang. A clean and efficient method for recovery of vanadium from vanadium slag: non-salt roasting and ammonium carbonate leaching processes. Mineral Processing and Extractive Metallurgy Review, 2017, 38: 228-237
28. Longjie Liu, Zhonghang Wang, Hao Du*, Shili Zheng, Ulla Lassi, Yi Zhang. Intensified decomposition of vanadium slag via aeration in concentrated NaOH solution. International Journal of mineral processing, 2017, 160: 1-7
29. Shaona Wang, Xuemei Guo, Hao Du*, Shili Zheng, Biao Liu, Yi Zhang. Solubility Investigations in the (NH4)2C2O4−NH4VO3−H2O System from 313.15 to 363.15 K. Journal of Chemical &Engineering Data, 2017, 62, 3313−3318
30. 王少娜，王亚茹，杜浩*，郑诗礼，张懿. 活性炭强化氧化亚熔盐介质中钒渣分解机理.中国有色金属学报，2017,8:1729-1737
31. 潘博，郑诗礼，王少娜，刘彪，杜浩*，张懿. Cr2O3在KOH溶液中电场强化溶出机理及溶出因素影响. 过程工程学报, 2016, 6(16): 933-940
32. Yeqing Lv，Shili Zheng，Shaona Wang，Wenyi Yan，Yi Zhang，Hao Du*. Vibrational spectra and molecular dynamics of hydrogen peroxide molecules at quartz/water interfaces. Journal of Molecular Structure，2016, 1113: 70-78
33. Biao Liu, Xuming Wang, Hao Du*, Jing Liu, Shili Zheng, Yi Zhang, Jan D. Miller. The surface of lead activation in amyl xanthate flotation of quartz. International Journal of Mineral Processing, 2016, 151: 33-39
34. Biao Liu, Shili Zheng, Shaona Wang, Yi Zhang, Hao Du*. The electrowinning of vanadium oxide from alkaline solution. Hydrometallurgy, 2016, 165: 244-250
35. Xinran Wang，Shili Zheng，Shaona Wang，Yi Zhang，Hao Du*. Self-ancho ring dendritic ternary vanadate compound on graphene nanoflake as high-performance conversion-type anode for lithium ion batteries. Nano Energy, 2016, 22: 179-188
36. Yeqing Lv, Shili Zheng, Shaona Wang, Hao Du*, Yi Zhang. Structure and Diffusivity of Oxygen in Concentrated Alkali-Metal Hydroxide Solutions: A Molecular Dynamics Simulation Study. Acta Physico-Chimica Sinica, 2015, 31(6): 1045-1053
37. Wenyi Yan，Shili Zheng，Wei Jin，Zhong Peng，Shaona Wang，Hao Du*，Yi Zhang. The influence of KOH concentration, oxygen partial pressure and temperature on the oxygen reduction reaction at Pt electrodes. Journal of Electroanalytical Chemistry, 2015, 741: 100-108
38. Zhonghang Wang, Shili Zheng, Shaona Wang, Yaling Qin, Hao Du*, Yi Zhang. Electrochemical decomposition of vanadium slag in concentrated NaOH solution. Hydrometallurgy, 2015, 151: 51-55
39. Lanjie Li, Shili Zheng, Shaona Wang, Hao Du*, Yi Zhang. Thermal hydrolysis synthesis and characterization of monoclinic metahewettite CaV6O16•3H2O. Journal of Wuhan University of Technology (Materials Science Edition), 2014, 29(3): 433-440
40. Zhong-hang Wang, Shi-li Zheng, Shao-na Wang, Biao Liu, Da-wei Wang, Hao Du*, Yi Zhang. Research and prospect on extraction of vanadium from vanadium slag by liquid oxidation technologies. Trans. Nonferrous Met. Soc. China, 2014, 24(5): 1273-1288
41. Zhong Peng, Wenyi Yan, Shaona Wang, Shili Zheng, Hao Du*, Yi Zhang.Effect of Alkali Concentration, Oxygen Partial Pressure and Temperature on Oxygen Reduction Reaction on Pt Electrode in NaOH Solution. Acta Physico -Chimica Sinica, 2014, 30(1): 67-74
42. Xinran Wang; Shili Zheng; Yi Zhang; Hao Du*. Hollow carbon nanofiber as stabilizer for in-situ TiO2/VO2 co-impregnation with high rate performance and ultra-long cycling life as lithium-ion battery anode. Journal of Materials Chemistry A, 2014, 2: 13232-13236
43. Xinran Wang; Shili Zheng; Xuechao Mu; Zhang, Yi Zhang; Hao Du*. Additive-free synthesis of V4O7 hierarchical structures as high performance cathodes for lithium ion batteries. Chem Commun (Camb), 2014, 50(51): 6775-6778
44. 潘自维，郑诗礼，王中行，王少娜，杜浩*，张懿，谢华. 亚熔盐法高铬钒渣钒铬高效同步提取工艺研究. 钢铁钒钛，2014, 35(02): 1-8
45. 潘自维，王大卫，杜浩*，陈刚，郑诗礼，王少娜，张懿. 活性炭强化钒渣中钒、铬提取技术. 中国有色金属学报，2014, 8: 2171-2180
46. 刘继鑫，李兰杰，郑诗礼，王少娜，杜浩*，谢海云. 钒渣焙烧-水热碱浸提钒. 过程工程学报，2014, 5: 763-769
47. 穆学超，王欣然，郑诗礼，王少娜，郭奋，杜浩*，张懿. 钙掺杂钒青铜超级电容器电极材料的制备及其性能. 过程工程学报，2013, 13(5): 882-888
48. 吕页清，郑诗礼，王少娜，杜浩*，张懿. METSIM在亚熔盐铬盐清洁生产工艺流程设计中的应用. 过程工程学报，2013, 1: 99-104
49. 刘挥彬，杜浩*，刘彪，王少娜，郑诗礼，张懿. KOH亚熔盐中钒渣的溶出行为. 中国有色金属学报，2013, 23(4): 1129-1139
50. 吕页清，郑诗礼，王少娜，杜浩*，张懿. METSIM在亚熔盐法钒渣清洁生产工艺流程设计中的应用. 过程工程学报，2013, 2: 270-274
51. Hui-bin LIU, Hao DU*, Da-wei WANG, Shao-na WANG, Shi-li ZHENG, Yi ZHANG. Kinetics analysis of decomposition of vanadium slag by KOH sub-molten salt method. Transactions of Nonferrous Metals Society of China, 2013, 23(5): 1489-1500
52. Biao Liu, Shili Zheng, Shaona Wang, Yi Zhang, Ada Ortega, Nam Soo Kim, Kenneth Han, Hao Du*. The redox behavior of vanadium in alkaline solutions by cyclic voltammetry method. Electrochimica Acta, 2012, 76: 262-269
53. Wei Jin, Michael S. Moats, Shili Zheng, Hao Du*, Yi Zhang, Jan D.Miller. Indirect electrochemical Cr(III) oxidation in KOH solutions at an Au electrode: The role of oxygen reduction reaction. The Journal of Physical Chemistry B, 2012, 116(25):7531-7537
54. 王中行，郑诗礼，杜浩*，王少娜，张懿. 新型钒材料研究进展. 钢铁钒钛，2012, 3: 98-106
55. 王大卫，郑诗礼，王少娜，杜浩*. 钒渣NaOH亚熔盐法提钒工艺研究. 中国稀土学报，2012, 30: 684-691
56. Wei Jin, Michael S. Moats, Shili Zheng, Hao Du*, Yi Zhang, Jan D. Miller. Modulated Cr(III) oxidation in KOH solutions at a gold electrode: Competition between disproportionation and stepwise electron transfer. Electrochimica Acta, 2011, 56(24):8311-8318
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